A review of anthropogenic radionuclide 236U: Environmental application and analytical advances

Abstract

²³⁶U is an anthropogenic radionuclide that is produced from nuclear reactions of ²³⁵U(n, γ) and ²³⁸U(n, 3n). It has gained extensive attention in the field of environment, geology, nuclear emergency, and nuclear forensics. Due to the unique physical and chemical character and the distinct fingerprint character from different sources, ²³⁶U has been successfully applied in the environmental tracer, nuclear material source appointment, and environmental assessment. Until now, few reviews were published about the database, application, and the latest analytical technology development of ²³⁶U. In this review, the ²³⁶U concentration and ²³⁶U/²³⁸U isotope ratio were summarized, and the data were classified into four categories, including soil and seawater samples affected by global fallout and nuclear incidents. Furthermore, the development of environmental application and pretreatment methods were also summarized. The advanced pretreatment technology using alkali fusion and flow injection was especially discussed to introduce the development of a rapid analytical method. Finally, the research challenge and direction of ²³⁶U were proposed for further research, such as the tracer application combining ²³⁶U with other radionuclides in the terrestrial environment and the precise analysis of minor isotopes in ultra-trace uranium samples. We hope this review will help scholars to have a deep research on the analysis and application of ²³⁶U.

Keywords: (236)U; Automatic purification; Rapid pretreatment; Tracer application.