2D Higher-Metal Nitride Nanosheets for Solar Steam Generation

Abstract

Higher-metal (HM) nitrides are a fascinating family of materials being increasingly researched due to their unique physical and chemical properties. However, few focus on investigating their application in a solar steam generation because the controllable and large-scale synthesis of these materials remains a significant challenge. Herein, it is reported that higher-metal molybdenum nitride nanosheets (HM-Mo₅ N₆ ) can be produced at the gram-scale using amine-functionalized MoS₂ as precursor. The first-principles calculation confirms amine-functionalized MoS₂ nanosheet effectively lengthens the bonds of MoS leading to a lower bond binding energy, promoting the formation of MoN bonds and production of HM-Mo₅ N₆ . Using this strategy, other HM nitride nanosheets, such as W₂ N₃ , Ta₃ N₅ , and Nb₄ N₅ , can also be synthesized. Specifically, under one simulated sunlight irradiation (1 kW m^-2 ), the HM-Mo₅ N₆ nanosheets are heated to 80 °C within only ≈24 s (0.4 min), which is around 78 s faster than the MoS₂ samples (102 s/1.7 min). More importantly, HM-Mo₅ N₆ nanosheets exhibit excellent solar evaporation rate (2.48 kg m^-2 h^-1 ) and efficiency (114.6%), which are 1.5 times higher than the solar devices of MoS₂ /MF.

Keywords: 2D nanosheets; functionalized MoS 2 nanosheets; higher-metal nitrides; mechanical exfoliation; solar steam generation.