High-efficiency and stable deep-blue bottom-emitting organic light-emitting diodes with Commission Internationale de l'Eclairage y coordinates (CIE y s) < 0.08 remain exclusive in the literature owing to the high excited-state energy of the emitters. Here, we propose the utilization of narrowband emitters to lower the excited-state energy for stable deep-blue devices by taking advantage of their high color purity. Two proof-of-concept deep-blue emitters with nitrogen-containing spiro-configured polycyclic frameworks are thereafter developed to introduce a multi-resonance effect for narrow emissions and sterically orthogonal configurations for alleviated molecular interactions. Both emitters show bright ultrapure deep-blue emissions with an extremely small full-width-at-half-maxima of only 18-19 nm, which can be maintained even in heavily doped films. Small CIE y s of 0.054 and 0.066 are therefore measured from the corresponding electroluminescence devices with peak energies of only 2.77 eV (448 nm) and 2.74 eV (453 nm), accounting for the remarkably long LT80s (lifetime to 80% of the initial luminance) of 18 900 and 43 470 hours at 100 cd m-2, respectively. Furthermore, by adopting a thermally activated delayed fluorescence sensitizer, impressive maximum external quantum efficiencies of 25% and 31% are recorded respectively, representing state-of-the-art performances for deep-blue devices.
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