Alloy-type anodes are one of the most promising classes of next-generation anode materials due to their ultrahigh theoretical capacity (2-10 times that of graphite). However, current alloy-type anodes have several limitations: huge volume expansion, high tendency to fracture and disintegrate, an unstable solid-electrolyte interphase (SEI) layer, and low Coulombic efficiency. Efforts to overcome these challenges are ongoing. This Review details recent progress in the research of batteries based on alloy-type anodes and discusses the direction of their future development. We conclude that improvements in structural design, the introduction of a protective interface, and the selection of suitable electrolytes are the most effective ways to improve the performance of alloy-type anodes. Furthermore, future studies should direct more attention toward analyzing their synergistic promoting effect.
Keywords: Alloy-Type Anodes; Batteries; Electrolytes; Protective Interfaces; Structural Design.
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