Reactive Flash Sintering of High-Entropy Oxide (Mg, Co, Ni, Cu, Zn)1-xLixO at Room Temperature

Materials (Basel). 2022 May 27;15(11):3836. doi: 10.3390/ma15113836.

Abstract

(Mg, Co, Ni, Cu, Zn)1-xLixO is a type of high-entropy oxide that has high ionic conductivity at room temperature and is used as a solid electrolyte. (Mg, Co, Ni, Cu, Zn)1-xLixO was successfully synthesized from precursor powder by applying reactive flash sintering for less than 4 min at room temperature (25 °C). AC and DC electric fields were independently applied to sinter ceramic samples; consequently, AC and DC electric field application resulted in relative densities that exceeded 90% and 80%, respectively. X-ray diffraction spectra of samples revealed the existence of a clear halite structure with an insignificant impurity phase, proving that (Mg, Co, Ni, Cu, Zn)1-xLixO crystals were successfully produced.

Keywords: alternating current field (AC); flash sintering; high entropy ceramics; room temperature.