A near-ambient pressure flow reactor coupled with polarization-modulation infrared reflection absorption spectroscopy for operando studies of heterogeneous catalytic reactions over model catalysts

Peng Chai; Yuekang Jin; Guanghui Sun; Liangbing Ding; Longxia Wu; Haocheng Wang; Cong Fu; Zongfang Wu; Weixin Huang

doi:10.1063/5.0081102

A near-ambient pressure flow reactor coupled with polarization-modulation infrared reflection absorption spectroscopy for operando studies of heterogeneous catalytic reactions over model catalysts

Rev Sci Instrum. 2022 May 1;93(5):054105. doi: 10.1063/5.0081102.

Authors

Peng Chai¹, Yuekang Jin¹, Guanghui Sun¹, Liangbing Ding¹, Longxia Wu¹, Haocheng Wang¹, Cong Fu¹, Zongfang Wu¹, Weixin Huang¹

Affiliation

¹ Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, People's Republic of China.

PMID: 35649779
DOI: 10.1063/5.0081102

Abstract

The model catalyst approach is often used for fundamental investigations of complex heterogeneous catalysis, in which operando characterizations are critical. A flow reactor is usually adopted for gas-solid heterogeneous catalytic reactions. Herein, we report a home-designed near-ambient pressure (NAP) flow reactor coupled with polarization-modulation infrared reflection absorption spectroscopy (PM-IRAS) and an online quadrupole mass spectrometer for operando studies of heterogeneous catalytic reactions over model catalysts. A unique gas supply system is designed and manufactured to enable a stable gas inlet to the NAP flow reactor at pressures up to ∼100 mbar. An ultrahigh vacuum chamber equipped with the facilities for x-ray photoelectron spectroscopy, low-energy electron diffraction, thermal desorption spectroscopy, E-beam evaporation source, and ion sputtering gun is connected to the NAP flow reactor via a gate valve for preparations and routine characterizations of model catalysts. The functions of the system are demonstrated by in situ PM-IRAS characterization of CO adsorption on Pt(111) and operando characterizations of CO oxidation on Pt(111) under NAP conditions.