Distribution characteristics, source identification, and risk assessment of heavy metals in surface sediments of the salt lakes in the Ordos Plateau, China

Abstract

Salt lakes considerably affect the regional climate, environment, and ecology of semiarid regions characterized by low rainfall and high evaporation. However, under the stresses of global change and human disturbance, anthropogenic pollution is the primary factor threatening the lake's ecological environment. Surface sediment samples collected from four salt lakes in the Ordos Plateau were used to investigate the salinity, concentration, pollution status, potential sources of heavy metals, and influencing factors. The surface sediments of Beida Pond and Gouchi Pond were weakly alkaline (pH < 9) due to the presence of Na₂SO₄, whereas those of Chaigannaoer and Hongjiannao were strongly alkaline (pH > 9) due to the presence of Na₂CO₃. The concentration range of Cr, Ni, Cu, Zn, As, Cd, and Pb in the sediment samples collected from the salt lakes in the Ordos Plateau followed the order of Cr > Zn > Ni > Pb > Cu > As > Cd. The Cr concentration values were higher in Chagannaoer and Hongjiannao; however, the Ni, Cu, and Zn values were higher in Beida Pond and Gouchi Pond. The geoaccumulation index (I_geo) and enrichment factor (EF) consistently indicated that Cr posed the greatest potential ecological risk and that Ni, Cu, and Zn pollution was more severe in Beida Pond and Gouchi Pond than in Chagannaoer or Hongjiannao. However, the ecological risk index and potential ecological risk value indicated that these heavy metals posed low risks to the environment. The risk assessment code (RAC) revealed that Pb and Cr exhibited no mobility and had low potential bioavailability risk. Meanwhile, Zn, Ni, and As were categorized as medium risk. Cu had the highest mobility and was categorized as high risk. Principal component analysis for the four salt lakes revealed that the source of Ni, Cu, Zn, and Cd might be associated with water-soluble elements associated with aqueous migration, while the source of Cr, Pb, and As might be the lithospheric minerals carried by dust storms. Pearson's correlation analysis indicated that clay minerals were the primary adsorbers of Ni, Cu, Zn, and Cd. Moreover, pH was identified as the main environmental factor controlling the distribution of heavy metals in the salt lakes.

Keywords: Heavy metals; Ordos Plateau; Pollution assessment; Salt lakes; Sediments; Sources.