One pot synthesis of UiO-66@IL composite for fabrication of CO2 selective mixed matrix membranes

Abstract

In this study, a facile and extensible one pot approach was utilized to synthesize ionic liquid inside a porous metal organic framework (UiO-66). Different characterization techniques were used to confirm the successful synthesis of UiO-66@IL composite. The MMMs were characterized and tested for CO₂ separation from CH₄ or N₂ at ambient and elevated temperatures. SEM images exhibited well dispersion of the filler particles with no notable defect even at high loadings. Single and mixed gas permeation results indicated significant performance (CO₂ permeability: 143 Barrer and CO₂/CH₄, CO₂/N₂ selectivity: 28.32, 61.11 respectively) by enhancing the permeability of CO₂ by 74% and selectivity to 31% and 26% for CO₂/CH₄ and CO₂/N₂ compared with neat Pebax®1657 membrane.

Keywords: CO(2) separation; Ionic liquid; MMMs; SIB technique; UiO-66.