Magneto-Dielectric Effects in Polyurethane Sponge Modified with Carbonyl Iron for Applications in Low-Cost Magnetic Sensors

Polymers (Basel). 2022 May 18;14(10):2062. doi: 10.3390/polym14102062.

Abstract

In this study, magnetizable polyurethane sponges (MSs) were obtained from commercial absorbent polyurethane sponges (PSs) doped with carbonyl iron microparticles (CIPs). Based on MSs, we manufactured cylindrical capacitors (CCs). The CCs were subjected to both a magnetic field and an alternating electric field, with a frequency of f=1 kHz. Using an RLC bridge, we measured the series electric capacitance, Cs, and the tangent of the loss angle, Ds. From the functions Cs=Cs(δ)CCs and Ds=Ds(δ)CCs, we extracted the components of the complex dielectric permittivity. It was found that the CIPs embedded in the MS matrix aggregated, leading to magneto-dielectric effects such as the enhancement of the complex dielectric permittivity components when applying the magnetic field as a principal effect and the enhancement of the electric capacitance and time constant of the capacitors as a secondary effect. The obtained results represent landmarks in the realization of low-cost magnetic field sensors, deformation and mechanical stress transducers in the robotics industry, etc.

Keywords: carbonyl iron; cylindrical capacitor; dielectric loss coefficient; polyurethane sponge; relative dielectric permittivity; static magnetic field.