Molybdenum disulfide (MoS2), with a two-dimensional (2D) structure, has attracted huge research interest due to its unique electrical, optical, and physicochemical properties. MoS2 has been used as a co-catalyst for the synthesis of novel heterojunction composites with enhanced photocatalytic hydrogen production under solar light irradiation. In this review, we briefly highlight the atomic-scale structure of MoS2 nanosheets. The top-down and bottom-up synthetic methods of MoS2 nanosheets are described. Additionally, we discuss the formation of MoS2 heterostructures with titanium dioxide (TiO2), graphitic carbon nitride (g-C3N4), and other semiconductors and co-catalysts for enhanced photocatalytic hydrogen generation. This review addresses the challenges and future perspectives for enhancing solar hydrogen production performance in heterojunction materials using MoS2 as a co-catalyst.
Keywords: heterojunction; hydrogen production; layers structure materials; photocatalysis.