Tuneable molecular selective boron nitride nanosheet ultrafiltration lamellar membrane for dye exclusion to remediate the environment

Abstract

Smart tuning of the membrane's porous nanostructures offers an effective strategy for creating state-of-the-art, high-performance separation membranes. In aqueous solution, polyethylene glycol (PEG) grafted boron nitride PEG_X-g-(f-BN) nanosheets exhibit high permeance and excellent molecular sieving. The molecular selectivity of the PEG_X-g-(f-BN) lamellar membrane is controlled by the nanopores, which can be tuned by modulating the interplanar spacing between the nanosheets. Herein, the interplanar spacing of h-BN nanosheets is enhanced in the range of 0.334-0.348 nm through grafting different molecular weight PEG. Moreover, the grafted PEG instigates a synergistic effect on the nanosheets in two ways. Firstly, through PEG intercalation, the interlayer spacing of the (002) plane could be adjusted without significant deterioration to the hexagonal crystallographic structure. Secondly, intercalated PEG in BN nanosheets reflects in terms of improved h-BN wettability through transformation to hydrophilic surface characteristics (small contact angle of 36-39°). The fabricated PEG_X-g-(f-BN) lamellar membrane acquires stable and interconnected nanopores and nanochannels with an average pore diameter of 1.36-2.19 nm. Permeance-exclusion trade-off manipulation through methodical approaches of PEG_X-g-(f-BN) decoration thickness and interplanar spacing is exploited to build a better understanding of water transport behavior. PEG_X-g-(f-BN) lamellar membranes show unprecedented permeance of ∼1253 L m^-2 h^-1 bar^-1 with a steady methyl blue (MB) exclusion of 98.9% even in different pH conditions.

Keywords: Boron nitride nanosheet; Desalination; Environmental remediation; Interplanar spacing expansion; Polyethylene glycol.