Recent advances of ordered mesoporous silica materials for solid-phase extraction

Abstract

This review mainly focuses on the development and application of ordered mesoporous silica materials for solid-phase extraction in recent years. It overviews not only bare mesoporous silica but also the functionalized mesoporous silica with organic groups, molecularly imprinted polymers, and magnetic materials. These mesoporous silica materials were used as the extraction adsorbents in cartridge solid-phase extraction, dispersive solid-phase extraction, magnetic solid-phase extraction, micro-solid-phase extraction and matrix solid phase dispersion. Coupled with atomic emission spectrometry, chromatography or other detection methods, these techniques efficiently extracted and sensitively determined various targets, such as metal ions, perfluorocarboxylic acids, pesticides, drugs, endocrine disruptors, phenols, flavanones, polycyclic aromatic hydrocarbons, parabens and so on. Based on unique advantages of mesoporous silica materials, the developed analytical method successfully analyzed different matrix samples, like environmental water samples, soil samples, food samples, biological samples and cosmetics. In addition, the prospects of these materials in solid-phase extraction are presented, which can offer an outlook for the further development and applications.

Keywords: Dispersive extraction; Magnetic extraction; Ordered mesoporous silica; Pollutant; Solid-phase extraction.