The aim of this study was to investigate the biomimetic precipitation processes that follow the chemical-garden reaction of brines of CaCl2 and sulfate salts with silicate in alkaline conditions under a Mars-type CO2-rich atmosphere. We characterize the precipitates with environmental scanning electron microscope micrography, micro-Raman spectroscopy, and X-ray diffractometry. Our analysis results indicate that self-assembled carbonate structures formed with calcium chloride can have vesicular and filamentary features. With magnesium sulfate as a reactant a tentative assignment with Raman spectroscopy indicates the presence of natroxalate in the precipitate. These morphologies and compounds appear through rapid sequestration of atmospheric CO2 by alkaline solutions of silica and salts.
Keywords: CO2 atmosphere; Carbonate minerals; Chemical gardens; Mars; Natroxalate; Self-assembly.