Rheological model for the alpha relaxation of glass-forming liquids and its comparison to data for DC704 and DC705

J Chem Phys. 2022 May 21;156(19):194502. doi: 10.1063/5.0090249.

Abstract

Dynamic shear-modulus data are presented for two silicone oils DC704 and DC705 for frequencies between 1 mHz and 10 kHz at temperatures covering more than five decades of relaxation-time variation. Data are fitted to the alpha part of a phenomenological model previously shown to describe well the dynamic shear modulus of squalane, which has a large beta process [Hecksher et al., J. Chem. Phys. 146, 154504 (2017)]. That model is characterized by additivity of the alpha and beta shear compliance and by a high-frequency decay of the alpha process in proportion to ω-1/2, where ω is the angular frequency. The fits of the alpha part of this model to the DC704 and DC705 data are compared to fits by a Havriliak-Negami type model, a Barlow-Erginsav-Lamb model, and a Cole-Davidson type model. At all temperatures, the best fit is obtained by the alpha part of the squalane model. This strengthens the conjecture that so-called t-relaxation, leading to high-frequency loss decays proportional to ω-1/2, is generic to the alpha relaxation of supercooled liquids [J. C. Dyre, Phys. Rev. E 74, 021502 (2006); Nielsen et al., J. Chem. Phys. 130, 154508 (2009); and Pabst et al., J. Phys. Chem. Lett. 12, 3685-3690 (2021)].