Nitrite reduction over Ag nanoarray electrocatalyst for ammonia synthesis

Abstract

Electrochemical reduction of nitrite to ammonia can simultaneously achieve ammonia synthesis and N-contaminant removal under mild conditions, which has attracted widespread attention but still lacks efficient catalysts. In this work, Ag nanoarray using NiO nanosheets array on carbon cloth as support is reported as an efficient electrocatalyst to selectively reduce nitrite to ammonia. In 0.1 M NaOH with 0.1 M NO₂^-, such catalyst exhibits a maximum ammonia yield of 5,751 μg h^-1 cm^-2 (57,510 μg h^-1 mg_Ag^-1) and high Faradaic efficiency up to 97.7 %. Density functional theory calculations applied to uncover the catalytic mechanism of NO₂^- reduction reaction on Ag.

Keywords: Ag nanoarray; Ammonia synthesis; Electrocatalysis; NiO nanosheets; Nitrite reduction reaction.