Generating polymer-metal structures by means of additive manufacturing offers huge potential for customized, sustainable and lightweight solutions. However, challenges exist, primarily with regard to reliability and reproducibility of the additively generated joints. In this study, the polymers ABS, PETG and PLA, which are common in material extrusion, were joined to grit-blasted aluminum substrates. Temperature dependence of polymer melt rheology, wetting and tensile single-lap-shear strength were examined in order to obtain appropriate thermal processing conditions. Joints with high adhesive strength in the fresh state were aged for up to 100 days in two different moderate environments. For the given conditions, PETG was most suitable for generating structural joints. Contrary to PETG, ABS-aluminum joints in the fresh state as well as PLA-aluminum joints in the aged state did not meet the demands of a structural joint. For the considered polymers and processing conditions, this study implies that the suitability of a polymer and a thermal processing condition to form a polymer-aluminum joint by material extrusion can be evaluated based on the polymer's rheological properties. Moreover, wetting experiments improved estimation of the resulting tensile single-lap-shear strength.
Keywords: ABS; PETG; PLA; additive manufacturing; aging; aluminum; material extrusion; polymer rheology; structural joints; thermal joining.