Rapid surface degradation of co-axially arranged polypropylene globules by nanoporous carbonized TiO2 assisted with UV-C

Abstract

The degradation of plastics, especially polypropylene (PP), is difficult since it is the most hydrophobic polymer. Photocatalytic degradation of PP films has been reported to be one of the most efficient degradation techniques. However, it is still insignificant to employ it in field applications. In this study, TiO₂ nanoparticles supported on amorphous carbon with nanoporosity (TiO₂@NC) are used as a photocatalyst to degrade macro-sized co-axially oriented PP globules under the influence of UV-C irradiation. Surface characterization such as SEM, ATR-FTIR, and XPS of the PP globules was performed. The SEM images distinctly showed the surface degradation phenomenon. Interestingly, the ATR-FTIR spectra demonstrated a significant rise in the band intensity in the -OH radical region and fairly in the CO region as well, with the increase in the photocatalytic time. Surprisingly, in the XPS spectra, the intensity of C-1s spectra kept on falling, and the intensity of O-1s spectra kept on rising with the increase in the photocatalytic time. The higher surface area due to nanoporosity of TiO₂@NC enhanced the photocatalytic degradation of PP globules than previously reported studies. TiO₂@NC seems to be a potential catalyst for the degradation of different types of polymers.

Keywords: Degradation; Nanoporous carbonized TiO(2); Photocatalysis; Polymer; Polypropylene globule.