It was previously believed that ammonia (NH3) has a short residence time in the atmosphere and cannot be transported far from its sources. In late March, however, this study observed a severe NH3 episode in urban Beijing when fertilizer was intensively applied on the North China Plain, with the highest hourly concentrations of 66.9 μg m-3 throughout the year. The stable nitrogen isotopic composition of NH3 (δ15N-NH3) during this episode (-37.0 to -20.0‰) fell in the range of endmembers of fertilizer and livestock, suggesting the long-range transport of NH3 from agricultural to urban regions. Based on a Bayesian isotope mixing model, the contribution of agriculture (fertilization) to urban NH3 concentrations was apportioned as 43.5% (26.0%) on polluted days. However, these contributions were reduced to 29.1% (12.8%) when nitrogen isotope fractionation between NH3 and ammonium was considered. In contrast to the limited contribution of agricultural sources, we found that nonagricultural emissions, particularly vehicles, dominate the source of NH3 in urban Beijing, even during the fertilization period. This finding indicated that nonagricultural sources should be considered when designing a control strategy for NH3 to reduce haze pollution in the urban atmosphere.
Keywords: Ammonia; Haze pollution; Isotope fractionation; Nitrogen isotope; Source apportionment.
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