Study on the Characteristics of the Dispersion and Conductivity of Surfactants for the Nanofluids

Nanomaterials (Basel). 2022 May 2;12(9):1537. doi: 10.3390/nano12091537.

Abstract

Given the importance of nanofluid dispersion and stability, a number of approaches were proposed and applied to the nanofluid preparation process. Among these approaches, the noncovalent chemical process was intensively utilized because of its effective dispersion ability. For the noncovalent dispersion method, polymers and surfactants are typically used. In order to find an effective noncovalent dispersion method, several types of solutions were prepared in this study. The widely used naturally cellulose nanocrystal (CNC) aqueous solution was compared with several surfactant aqueous solutions. The dispersion characteristics of the prepared fluids were examined by UV/VIS spectroscopy at operating wavelengths ranging from 190 to 500 nm. Furthermore, the heat capacity and the electrical and thermal conductivity of the fluids were analyzed to evaluate their heat transfer performance and conductivity. The Lambda system was utilized for thermal conductivity measurement with operation at proper temperature ranges. The electrical conductivity of the fluids was measured by a conductivity meter. This experimental study revealed that the cellulose nanocrystal was an effective source of the noncovalent dispersion agent for thermal characteristics and was more eco-friendly than other surfactants. Moreover, cellulose aqueous solution can be used as a highly thermal efficient base fluid for nanofluid preparation.

Keywords: cellulose; dispersion; heat transfer performance; nanofluid; surfactant.