Facile Synthesis of Green Fluorescent Carbon Dots and Their Application to Fe3+ Detection in Aqueous Solutions

Nanomaterials (Basel). 2022 Apr 27;12(9):1487. doi: 10.3390/nano12091487.

Abstract

Carbon dots (CDs), a class of fluorescent nanomaterials, have attracted widespread attention from researchers. Because of their unique chemical properties, these high-quality fluorescent probes are widely used for ion and molecule detection. Excess intake of many ions or molecules can cause harm to the human body. Although iron (in the form of Fe3+ ions) is essential for the human body, excess iron in the human body can cause many diseases, such as iron poisoning. In this study, we have synthesized fluorine and nitrogen co-doped carbon dots (FNCDs) by a hydrothermal method. These FNCDs exhibited good stability, selectivity, and anti-interference ability for Fe3+. Fe3+ could be detected in the range of 0.2-300 μM, and their detection limit is up to 0.08 μM. In addition, the recovery and relative standard deviation measured by the standard addition recovery method were not higher than 107.5% and 1.1%, respectively, indicating that FNCDs have good recovery and accuracy for Fe3+ detection.

Keywords: Fe3+; carbon dot; fluorescence spectrum; fluorescent probe; ions detection.