A chemiresistive sensor array based on polyaniline nanocomposites and machine learning classification

Beilstein J Nanotechnol. 2022 Apr 27:13:411-423. doi: 10.3762/bjnano.13.34. eCollection 2022.

Abstract

The selective detection of ammonia (NH3), nitrogen dioxide (NO2), carbon oxides (CO2 and CO), acetone ((CH3)2CO), and toluene (C6H5CH3) is investigated by means of a gas sensor array based on polyaniline nanocomposites. The array composed by seven different conductive sensors with composite sensing layers are measured and analyzed using machine learning. Statistical tools, such as principal component analysis and linear discriminant analysis, are used as dimensionality reduction methods. Five different classification methods, namely k-nearest neighbors algorithm, support vector machine, random forest, decision tree classifier, and Gaussian process classification (GPC) are compared to evaluate the accuracy of target gas determination. We found the Gaussian process classification model trained on features extracted from the data by principal component analysis to be a highly accurate method reach to 99% of the classification of six different gases.

Keywords: feature extraction; gas sensor; pattern recognition; sensor array.

Grants and funding

This work was supported by the Czech Science Foundation project No. GA22-04533S „Printed heterogeneous gas sensor arrays with enhanced sensitivity and selectivity“, by the grant of CTU No. SGS20/176/OHK3/3T/13, by the project Centre of the Advanced Applied Natural Sciences No. CZ.02.1.01/0.0/0.0/16_019/0000778 supported by the Operation Programme Research, Development and Education co-financed by European Comunity and by Ministry of Education Czech Republic and by the grant CzechNanoLab Research Infrastructure supported by MEYS CR (LM2018110).