Interfacial tension and CO2 diffusion coefficients for a CO2 + water and n-decane system at pressures of 10 to 160 bar

Abstract

The objective of this study is to address the influence of different CO₂ phases and degrees of CO₂ saturation on the interfacial tension and the diffusion of CO₂ into a hydrocarbon drop. Axisymmetric drop shape analysis on a pendant drop was used to carry out experiments in a pressure range of 10 to 160 bar and temperatures of 25 °C, 35 °C, and 45 °C, thus covering the gaseous, liquid, and supercritical phases of CO₂. A numerical model that estimates the diffusion coefficient of CO₂ in the hydrocarbon was developed. The IFT between the carbonated water and the hydrocarbon increases with pressure in the gaseous phase of CO₂ and decreases in the liquid and supercritical CO₂ phases. Interestingly, when the pressure was increased above 120 bar, the IFT did not change (decrease); this indicates that above this pressure, complete miscibility may not be achieved for this system, as indicated by the stable IFT. From the results, it can be concluded that the maximum IFT, maximum density decrease, and minimum diffusion coefficient occurred at pressures near to and below the phase change pressure of CO₂ (64 bar at 25 °C and 74 bar at 35 °C and 45 °C). Both CO₂-water-hydrocarbon and CW-hydrocarbon systems show the same trends; however, there were significant differences in the CO₂ mass transfer rate and the concentration gradient.