According to classical heterogeneous nucleation theory, the free energy barrier (ΔGc) of heterogeneous nucleation of vapor condensation ascends dramatically as the substrate nanostructure diameter (Rs) decreases. Based on this idea, we fabricated two types of superhydrophobic surfaces (SHSs) on an aluminum substrate by different roughening processes and the same fluorization treatment. Water vapor condensation trials by optical microscope and ESEM confirmed that on SHSs with submicron rectangle structures, a typical self-propelled motion of condensates or jumping condensation occurred. However, on SHS with coral-like micro/nano-structures, vapor nucleation occurred tardily, randomly, and sparsely, and the subsequent condensation preferentially occurred on the nuclei formed earlier, e.g., the condensation on such SHS typically followed the Matthew effect. Higher vapor-liquid nucleation energy barrier caused by smaller fluorinated nanostructures should be responsible for such a unique "anti-condensation" property. This study would be helpful in designing new SHSs and moving their application in anti-icing, anti-fogging, air humidity control, and so on.
Keywords: aluminum; anti-condensation; microscopic mechanism; smaller nanostructures; superhydrophobic surface.
Copyright © 2022 Li, Zhao, Yang and Feng.