Ternary dual Z-scheme graphitic carbon nitride/ultrathin metal-organic framework nanosheet/Ag3PO4 photocatalysts for boosted photocatalytic performance under visible light

Tomoharu Kusutaki; Hideyuki Katsumata; Ikki Tateishi; Mai Furukawa; Satoshi Kaneco

doi:10.1039/c9ra08292a

Ternary dual Z-scheme graphitic carbon nitride/ultrathin metal-organic framework nanosheet/Ag₃PO₄ photocatalysts for boosted photocatalytic performance under visible light

RSC Adv. 2019 Dec 2;9(68):39843-39853. doi: 10.1039/c9ra08292a.

Authors

Tomoharu Kusutaki¹, Hideyuki Katsumata¹, Ikki Tateishi², Mai Furukawa¹, Satoshi Kaneco^{1

2}

Affiliations

¹ Department of Chemistry for Materials, Graduate School of Engineering, Mie University Tsu Mie 514-8507 Japan hidek@chem.mie-u.ac.jp +81-59231-9425 +81-59231-9425.
² Mie Global Environment Center for Education & Research, Mie University Tsu Mie 514-8507 Japan.

Abstract

Ternary graphitic carbon nitride/ultrathin metal-organic framework nanosheet/Ag₃PO₄ (CNUA) composite photocatalysts were prepared under ultrasonic irradiation in tetrahydrofuran. The aim was to use them as photocatalysts for the degradation of organic pollutants in water. The crystal structure, surface morphology, optical properties, and chemical composition of the photocatalytic materials were investigated using X-ray diffraction, scanning electron microscopy, UV-vis diffuse reflectance spectroscopy, and X-ray photoelectron spectroscopy (XPS). The XPS analysis revealed the formation of Ag nanoparticles, which play an important role as an electronic mediator and photosensitizer in the composite during the synthesis. The photocatalytic activity of the composites in the degradation of 2-chlorophenol (2-CP) under visible light (>420 nm) was evaluated. Among the synthesized photocatalysts, the optimized CNUA with 10 wt% of g-C₃N₄ with respect to Ag₃PO₄ (CN10UA), exhibited the best photocatalytic performance in the degradation of 2-CP, which was almost decomposed completely upon ∼5 min of visible-light irradiation. Furthermore, the stability of the CN10UA photocatalyst could be maintained at a high level even after four cycling experiments, while that of pure Ag₃PO₄ declined significantly. The enhanced photocatalytic performance results from efficient charge separation through the dual Z-scheme mechanism involving Ag(0) bridges in the g-C₃N₄/Ag/Ag₃PO₄ and Ag₃PO₄/Ag/UMOFN pathways. The analysis of the photoluminescence of the catalysts also provided evidence for charge transport via the dual Z-scheme mechanism. In addition, radical scavenging tests confirmed that h⁺ and O₂˙^- are the main radical reactive species responsible for the photodegradation of 2-CP. The findings of this study enhance our understanding of the construction and mechanism of dual Z-scheme-type photocatalysts.