Unique and Excellent Paintable Liquid Metal for Fluorescent Displays

ACS Appl Mater Interfaces. 2022 May 10. doi: 10.1021/acsami.2c02714. Online ahead of print.

Abstract

A liquid metal (LM) generally has excellent electrical conductivity, thermal conductivity, flexibility, fluidity, and reflectivity. Innovative electronics using a LM to paint colorful fluorescent patterns may be applied to many important fields. Herein we propose, for the first time, the use of a LM to paint fluorescent patterns in the field of natural science. An LM containing a main-group metal (Ga50.25Bi8.28In28.2Sn13.27) is used to paint a uniform alloy film on a ceramic substrate. The painting is not restricted by any curved surface, shape, or size, which therefore gives the LM diverse adaptability. We have adopted the strategy of "painting-annealing-dealloying" through which LM can easily be diffused and doped into the substrate to produce various defects. Defects, my themselves or through their interactions, can produce different colors of emitted light. The primary fluorescence colors, such as purple, yellow, blue, and white, have been painted with the LM. Importantly, the brightness and color coordinates can be adjusted by changing the LM composition or annealing temperature, and intricate, delicate, colorful fluorescence patterns can be produced. Due to the unique painting form, colorful fluorescence, high stability, corrosion resistance, and low cost of the technique used for the LM, it can be used for displays, lighting panels, flexible electronic circuits, anticounterfeiting devices, and sensors.

Keywords: defects; fluorescence display; light emission; liquid metal; painting.