Acetylene hydrochlorination over boron-doped Pd/HY zeolite catalysts

RSC Adv. 2019 Sep 25;9(52):30335-30339. doi: 10.1039/c9ra05576b. eCollection 2019 Sep 23.

Abstract

A novel boron-doped Pd/HY zeolite catalyst for acetylene hydrochlorination was prepared and exhibited an outstanding catalytic performance (the acetylene conversion was maintained at >95% for about 30 h). The boron species can stabilize catalytically active Pd2+ species and weaken carbon deposition and Pd2+ reduction during the reaction, thus improving the catalytic stability.