Preparation of an Fe2Ni MOF on nickel foam as an efficient and stable electrocatalyst for the oxygen evolution reaction

Xintong Ling; Feng Du; Yintong Zhang; Yan Shen; Tao Li; Ahmed Alsaedi; Tasawar Hayat; Yong Zhou; Zhigang Zou

doi:10.1039/c9ra07499f

Preparation of an Fe₂Ni MOF on nickel foam as an efficient and stable electrocatalyst for the oxygen evolution reaction

RSC Adv. 2019 Oct 18;9(57):33558-33562. doi: 10.1039/c9ra07499f. eCollection 2019 Oct 15.

Authors

Xintong Ling^{1

2}, Feng Du^{1

2}, Yintong Zhang^{1

2}, Yan Shen^{2

3}, Tao Li⁴, Ahmed Alsaedi⁵, Tasawar Hayat^{5

6}, Yong Zhou^{1

2

7}, Zhigang Zou^{1

2

7}

Affiliations

¹ School of Physics, National Laboratory of Solid State Microstructures, Nanjing University Nanjing Jiangsu 210093 P. R. China zhouyong1999@nju.edu.cn.
² Jiangsu Key Laboratory for Nano Technology, Nanjing University Nanjing Jiangsu 210093 P. R. China.
³ College of Engineering and Applied Sciences, Nanjing University Nanjing 210093 P. R. China.
⁴ Engineering Technology Research Center of Henan Province for Solar Catalysis, School of Chemistry and Pharmaceutical Engineering, Nanyang Normal University Nanyang Henan 473061 P. R. China ltao84@163.com.
⁵ Faculty of Science, King Abdulaziz University Jeddah 21589 Saudi Aribia.
⁶ Department of Mathematics, Quaid-I-Azam University Islamabad 45320 Pakistan.
⁷ Kunshan Innovation Institute of Nanjing University Kunshan Jiangsu 215347 P. R. China.

Abstract

Metal-organic frameworks (MOFs) as versatile templates for preparing transition metal compounds has received wide attention. Benefiting from their diversified spatial structure and controllable chemical constituents, they have become a research hotspot in the field of electrocatalytic water splitting. Herein, Fe₂Ni-MIL-88B MOF on nickel foam (Fe₂Ni MOF/NF) has been prepared through a one-pot method growth process. Compared with Fe MOF/NF and Ni MOF/NF, the interaction between Fe³⁺ and Ni²⁺ in Fe₂Ni MOF/NF accelerates the electron transfer through the oxygen of the ligand, leading to increased 3d orbital electron density of Ni, which enhances the activity of the oxygen evolution reaction (OER) in alkaline solution. Fe₂Ni MOF/NF provides a current density of 10 mA cm^-2 at a low overpotential of 222 mV, and its Tafel slope is also very small, reaching 42.39 mV dec^-1. The success of the present Fe₂Ni MOF/NF catalyst is attributed to the abundant active centers, the bimetallic clusters Fe₂Ni-MIL-88B, the positive coupling effect between Ni and Fe metal ions in the MOF, and synergistic effect between the MOF and NF. Besides, Fe₂Ni MOF/NF possesses excellent stability over 50 h of continuous operation, providing feasibility for commercial use.