Two effective and one-step-synthesized organogelators based on d-gluconic acetal derivatives have been developed to show phase-selective gelation behaviours towards aromatic solvents from their biphasic mixtures with water. The dominant factors that drive gelation have been studied using FT-IR and temperature-dependent 1H NMR spectroscopy. Particularly, gelator GAA-2 in powder form could selectively congeal toluene, benzene and o-xylene at room temperature under mild stirring. Additionally, GAA-2 could gelate the aromatic solvents within 10 min and the recovery rate of the aromatic solvents could reach about 82% under a certain condition. The benefits of wide source availability, being easy to synthesize, and recyclable performance of the gelator make GAA-2 ideal for real-world remediation of aromatic solvents.
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