Polyaniline gels with a three-dimensional network structure are attractive for their broad application prospects in flexible and stretchable electric devices. In this paper, we develop a facile solution assembly method to prepare an elastic polyaniline/poly(vinyl alcohol) composite organogel and a hydrogel. The polyaniline and poly(vinyl alcohol) chains gelate from the homogeneous mixed solution in N-methyl-2-pyrrolidone via crystallization of poly(vinyl alcohol), producing a uniform organogel with hydrogen bonds between two polymers, and the organogel can be further converted into a hydrogel by solvent exchange. The composite gels exhibit excellent mechanical properties, which make them one of the best materials for additive manufacture, such as molding and 3D printing. This study develops an efficient method to fabricate polyaniline gels with good processability and multifunctions.
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