Spectroscopic data of norbornene and oxanorbornene dicarboximides functionalized with carbazole and coumarin groups

Rubina Troiano; Mario Carratù; Stefania Pragliola; Antonella Caterina Boccia; Fabia Grisi

doi:10.1016/j.dib.2022.108202

Spectroscopic data of norbornene and oxanorbornene dicarboximides functionalized with carbazole and coumarin groups

Data Brief. 2022 Apr 22:42:108202. doi: 10.1016/j.dib.2022.108202. eCollection 2022 Jun.

Authors

Rubina Troiano¹, Mario Carratù¹, Stefania Pragliola¹, Antonella Caterina Boccia², Fabia Grisi¹

Affiliations

¹ Dipartimento di Chimica e Biologia "Adolfo Zambelli", Università di Salerno, Via Giovanni Paolo II 132, I-84084 Fisciano, Salerno, Italy.
² Istituto di Scienze e Tecnologie Chimiche "G. Natta" (SCITEC), Consiglio Nazionale delle Ricerche, Via A. Corti, 12, 20133 Milano, Italy.

Abstract

This article describes data related to the research paper entitled "ROMP of norbornene and oxanorbornene derivatives with pendant fluorophore carbazole and coumarin groups" [1]. Six novel norbornene and oxanorbornene dicarboximides derivatives functionalized with carbazole or coumarin moieties, are synthesized and investigated in the preparation of fluorescent polymers by Ring-Opening Metathesis Polymerization (ROMP). Herein, we report on the characterization of all these compounds by 1D and 2D Nuclear Magnetic Resonance (NMR), UV-Visible and fluorescence spectroscopy. The characterization data include information obtained from ¹H, ¹³C, Homonuclear Correlation Spectroscopy (¹H-¹H COSY) and Heteronuclear Single Quantum Coherence (¹H-¹³C HSQC). The absorbence and fluorescence spectra for all these compounds are given. This work provides useful characterization data for the design of new norbornene and oxanorbornene-based monomers with fluorescent carbazole and coumarin groups, which can be employed for the synthesis of functional materials via ROMP.

Keywords: Carbazole and coumarin groups; Fluorescence; NMR spectroscopy; ROMP; UV-Vis.