The review describes the synthesis and properties of various forms of polyphenylsilsesquioxane (PPSQ). Among the forms described, we present the well-known ladder (l-PPSQ) and polyhedral (p-PPSQ) forms, from the first studies to the latest achievements. The practical prospects of these compounds and the possibility of their modification are estimated. These PPSQ have a regular polycyclic structure, which allowed us to compare them with random polycyclic analogs (r-PPSQ). The last part of the review describes the acyclic PPSQ (a-PPSQ) obtained recently. The methods for their synthesis and modification are presented. Modification of (a-PPSQ) allows two new forms of PPSQ to be obtained. The first one is a hyperbranched PPSQ. The second one is a globular PPSQ or a nanogel as it is called by the authors. Both forms are of great interest because their physicochemical properties differ greatly from the known ones (l-PPSQ, p-PPSQ, r-PPSQ). The areas of practical application of the new PPSQ forms are predicted.
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