Removal of PFASs from water by carbon-based composite photocatalysis with adsorption and catalytic properties: A review

Abstract

Per- and polyfluoroalkyl substances (PFASs) are a class of persistent organic pollutants widely distributed in aquatic environments. The adsorption and photocatalytic methods have been widely used to remove PFASs in water because of their respective advantages. Still, they have apparent defects when used alone. Therefore, the adsorption and photocatalytic technologies are combined through suitable preparation methods, and the excellent properties of the two are used to synergize the treatment of organic pollutants. This strategy of "concentrating" pollutants and then degrading them in a centralized manner plays an essential role in removing trace PFASs. Nevertheless, a review focusing on this kind of adsorption photocatalyst system is lacking. This review will fill this gap and provide a reference for developing a carbon-based composite photocatalyst. Firstly, different carbon-based composite photocatalysts are reviewed in detail, focusing on the differences in various composite materials' excellent adsorption and catalytic properties. Secondly, the factors influencing the removal effect of carbon-based composite photocatalysts are discussed. Thirdly, the removal mechanism of carbon-based composite photocatalysts is summarized in detail. The removal process involves two steps: adsorption and photodegradation. The adsorption process involves multiple cooperative adsorption mechanisms, and photocatalytic degradation includes oxidative and reductive degradation. Fourthly, the comparison of adsorption-photocatalysis with common treatment techniques (including removal rate, range of adaptation, cost, and the possibility of expanding application) is summarized. Finally, the prospects of carbon-based composite photocatalysts for repairing PFASs are given by evaluating the performance of different composites.

Keywords: Adsorption; Carbon materials; Composites; PFASs; Photocatalysis.