High-poly-aluminum chloride sulfate coagulants and their coagulation performances for removal of humic acid

Zhen Wu; Xian Zhang; Jinglin Pang; Juan Li; Jiding Li; Panyue Zhang

doi:10.1039/c9ra10189f

High-poly-aluminum chloride sulfate coagulants and their coagulation performances for removal of humic acid

RSC Adv. 2020 Feb 18;10(12):7155-7162. doi: 10.1039/c9ra10189f. eCollection 2020 Feb 13.

Authors

Zhen Wu^{1

2}, Xian Zhang^{1

2}, Jinglin Pang¹, Juan Li³, Jiding Li⁴, Panyue Zhang³

Affiliations

¹ Department of Chemical Engineering, Ordos Institute of Technology Ordos 017000 China hnuzx1101@163.com panyue_zhang@bjfu.edu.cn +86 18647722156.
² Department of Water Resources & Environmental Treatment, Redbud Innovation Institute Ordos 017000 China.
³ College of Environmental Science and Engineering, Beijing Forestry University Beijing 100083 China.
⁴ Department of Chemical Engineering, Tsinghua University Beijing 100084 China.

Abstract

High-poly-aluminum chloride sulfate (HPACS) coagulants with different [SO₄ ^2-]/[Al³⁺] molar ratio (S) were prepared and proved to have high coagulation efficiency for the removal of humic acid and strong stability for storage and application. The results showed that the higher the SO₄ ^2- addition, the bigger the aluminum polymerization particles and the more the polymerization Al_c existed in the prepared HPACS coagulants. The HPACS exhibited higher coagulation efficiency, a better aging stability and stronger resistance to the change of pH and Ca²⁺ concentration of raw water than the polyaluminum chloride (PAC) and poly-aluminum chloride sulfate (PACS) reported before. The Sips adsorption neutralization model was established to illustrate the relationship between coagulant dosage and zeta potential of the water system. The adsorption neutralization capacity was proved to be HPACS (S = 0) > HPACS (S = 0.02) > HPACS (S = 0.06) > HPACS (S = 0.10), which was not completely consistent with the coagulation effect of HPACS with different S values and indicated that in addition to adsorption neutralization, actions like bridge-aggregation, precipitation, and sweep-flocculation also played an important role during HPACS coagulation. Moreover, the negative Gibbs free energy indicated that the coagulant adsorption neutralization reaction was a spontaneous process.