Electrochemical Performance of MnO2/Graphene Flower-like Microspheres Prepared by Thermally-Exfoliated Graphite

Abstract

To enhance the electrochemical performance of MnO₂/graphene composite, herein, thermally-exfoliated graphite (TE-G) is adopted as a raw material, and a hydrothermal reaction is conducted to achieve the exfoliation of TE-G and the loading of MnO₂ nanosheets. Through optimizing the TE-G/KMnO₄ ratio in the redox reaction between carbon and KMnO₄, flower-like MnO₂/G microspheres (MnO₂/G-10) are obtained with 83.2% MnO₂ and 16.8% residual graphene. Meanwhile, corresponding MnO₂/rGO composites are prepared by using rGO as raw materials. Serving as a working electrode in a three-electrode system, MnO₂/G-10 composite displays a specific capacitance of 500 F g^-1 at 1 A g^-1, outstanding rate performance, and capacitance retention of 85.3% for 5,000 cycles. The performance is much better than that of optimized MnO₂/rGO composite. We ascribe this to the high carbon fraction in TE-G resulting in a high fraction of MnO₂ in composite, and the oxygen-containing groups in rGO reduce the resulting MnO₂ fraction in the composite. The superior electrochemical performance of MnO₂/G-10 is dependent on the hierarchical porous structure constructed by MnO₂ nanosheet arrays and the residual graphene layer in the composite. In addition, a supercapacitor assembled by TE-G negative electrode and MnO₂/G positive electrode also exhibits superior performance. In consideration of the low cost of raw materials, the MnO₂/G composite exhibits great application potential in the field of supercapacitors.

Keywords: MnO2; electrochemical performance; flower-like microspheres; supercapacitors; thermally-exfoliated graphite.