A mechanism for carbamazepine (CBZ) sorption by mangrove plant residue-derived biochars pyrolyzed at 200-700 °C (referred as MPR200-MPR700) was elucidated in this study. The experimental results demonstrated that the dominant sorption mechanism of biochars for CBZ was evolved from partition to adsorption with increasing pyrolysis temperature. The CBZ concentration-dependent contributions of partition and adsorption were controlled by the relative noncarbonized and carbonized fractions of biochars. The partition medium changed from a polymeric aliphatic fraction (mangrove plant residue [MPR]200-MPR400) to a more condensed aromatic phase (MPR500-MPR600), which made the partition less favorable. Meanwhile, the adsorption was selectively regulated by polarity (MPR200-MPR300) and porosity (MPR400-MPR700) for different biochars. A pragmatic model including the sorbent aromaticity index (H/C) was put forward to predict CBZ sorption to MPR200-MPR700 and other carbonaceous materials reported in the literature. The findings can be helpful in understanding CBZ-biochar interactions and developing effective sorbents (such as biochars) for pollutant sequestration.
© 2022 The Authors. Journal of Environmental Quality © 2022 American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.