Volatile organic compounds (VOCs) in indoor air are considered a major threat to human health and environmental safety. The development of applicable technologies for the removal of VOCs is urgently needed. Nowadays, photocatalytic oxidation (PCO) based on metal-containing photocatalysts has been regarded as a promising method. However, unmodified photocatalysts are generally limited in applications because of the narrow light response range and high recombination rate of photo-generated carriers. As a result, nano metal-containing photocatalysts doped with elements or other materials have attracted much attention from researchers and has developed over the past few decades. In addition, different doping types cause different levels of catalyst performance, and the mechanism for performance improving is also different. However, there are few reviews focusing on this aspect, which is really important for catalyst design and application. This work aims to give a comprehensive overview of nano metal-containing photocatalysts with different doping types for the removal of VOCs in an indoor environment. First, the undoped photocatalysts and the basic mechanism of PCO is introduced. Then, the application of metal doping, non-metal doping, co-doping, and other material doping in synthetic metal-containing photocatalysts are discussed and compared, respectively, and the synthesis methods, removal efficiency, and mechanisms are further investigated. Finally, a development trend for using nano metal-containing photocatalysts for the removal of VOCs in the future is proposed. This work provides a meaningful reference for selecting effective strategies to develop novel photocatalysts for the removal of VOCs in the future.
Keywords: VOCs; doping; mechanisms; photocatalysts; photocatalytic oxidation.