This study examines the atomic confinement of commercial Pt/C electrocatalysts. While a high electrocatalytic activity for the oxygen reduction reaction is important for proton-exchange membrane fuel cell (PEMFC) performance, the high stability of the electrocatalyst is essential for real applications under harsh operating conditions. The demands necessitate the development of advanced electrocatalysts that are resistant to corrosion. A combination of diazonium chemistry with Cu electrodeposition permits the selective protection of the carbon surface of the commercial Pt/C to prevent corrosion while improving wettability and ionic transfer. The resulting electrocatalysts exhibit an exceptional ORR stability after accelerated stress testing (AST) with a 250% improvement in comparison with unprotected commercial Pt/C. This novel electrochemical pathway provides a much-needed boost to carbon-based catalytic supports, which still face several stability challenges in energy applications in a harsh environment.
Keywords: Pt; carbon; corrosion; diazonium; electrocatalyst; fuel cell; nanomaterials; oxygen reduction reaction.