Removal of Uranium-238, Thorium-232, and Potassium-40 from Wastewater via Adsorption on Multiwalled Carbon Nanotubes

Saad S M Hassan; Ehab M Abdel Rahman; Gehan M El-Subruiti; Ayman H Kamel; Hanan M Diab

doi:10.1021/acsomega.2c00819

Removal of Uranium-238, Thorium-232, and Potassium-40 from Wastewater via Adsorption on Multiwalled Carbon Nanotubes

ACS Omega. 2022 Apr 1;7(14):12342-12353. doi: 10.1021/acsomega.2c00819. eCollection 2022 Apr 12.

Authors

Saad S M Hassan¹, Ehab M Abdel Rahman², Gehan M El-Subruiti³, Ayman H Kamel¹, Hanan M Diab²

Affiliations

¹ Chemistry Department, Faculty of Science, Ain Shams University, 11566 Cairo, Egypt.
² Central Laboratory for Environmental Radioactivity Measurements Inter-Comparison and Training (CLERMIT), Nuclear and Radiological Regulatory Authority, 11762 Cairo, Egypt.
³ Chemistry Department, Faculty of Science, Alexandria University, 45183 Alexandria, Egypt.

Abstract

The optimum conditions for the removal of uranium-238, thorium-232, and potassium-40 from wastewater and the discharge of nuclear facilities using multiwalled carbon nanotubes (CNTs) are described. The adsorption mechanism is mainly attributed to chemical interactions between the metal ions and surface functional groups of the CNTs. Batch adsorption experiments are carried out in order to study the effect of different parameters such as pH, contact time, initial metal ion concentration, adsorbent dose, and temperatures. Maximum metal removal (>98%) from solutions containing 20-120 Bq/L metal ions is achieved using a contact time of 15 min, a pH of 6.0, and 10 mg/L CNTs. The effect of temperature on the kinetics and equilibrium of adsorption on CNT particles is examined. Consistent with an exothermic reaction, an increase in the temperature resulted in an increase in the adsorption rate. Langmuir, Freundlich, and Dubinin-Radushkevich isotherms are applied to the data obtained at various temperatures. The Langmuir adsorption model is the best for data interpretations. The kinetics of adsorption reveals a pseudo-second-order mechanism. Thermodynamic parameters at 293 K (ΔG°, ΔH°, and ΔS°) for U-238, Th-232, and K-40 are -14590.7 kJ/mol, -6.66 kJ/mol, and 26.47 J/(mol K), -96,96.5 kJ/mol, -2.48 kJ/mol, and 14.17 J/(mol K), and -3922.09 kJ/mol, -1.32 kJ/mol, and 6.12 J/(mol K), respectively.