Diamond in the rough: Polishing waste polyethylene terephthalate into activated carbon for CO2 capture

Abstract

The scientific community has believed the potential of waste PET plastics as an effective carbon precursor, however, developing PET-derived activated carbons (PETACs) for a specific application is still a challenge we are facing. To overcome the limitation, a whole chain from development method screening to experiments design, finally to sample optimization, for a sample with promising performance, is proposed in this work. By employing PETACs as CO₂ adsorbents, the waste PET plastics, which we believed the "diamond in the rough", have been polished successfully. Therewith the problems of plastic pollution and the greenhouse effect could be simultaneously solved. The first half part of this paper is a mini review: the PETACs development methods were reviewed and the most suitable solution to develop CO₂ adsorbent, i.e., the two-step chemical activation method, was selected. In addition to that, the necessary procedure variables and their value range were determined. In the second half part, the central composite design method was applied for experiments design in which the procedure variables obtained were regarded as the independent indicators (factors here) while the performance indicators, including yield, CO₂ adsorption uptake, and CO₂ over N₂ selectivity, were treated as the dependent indicators (responses here). The responses were obtained through the characterization of the samples developed and statistical analysis could be applied to reveal the relations between the factors and responses. A high-value PETAC, P600K600-1.5, with the highest gas selectivity (22.189) and decent CO₂ adsorption uptake (3.933 mmol/g) was successfully designed.

Keywords: Activated carbon; CO(2) adsorption; Central composite design; PET plastic waste; Procedure optimization.