Cathode interface layers (CILs) are important for electron extraction in polymer solar cells (PSCs). Currently, the thickness of CILs is often below 15 nm due to their low electron mobility, which is not favorable for large-scale fabrication. Herein, we report a thick CIL for efficient PSCs by modifying the ZnO nanocrystals (NCs) film with perylene diimides functionalized with amino oxide (PDINO). The combined ZnO NCs/PDINO CIL inherits the high electron mobility of ZnO NCs and dense morphology of PDINO, affording higher power conversion efficiencies (PCEs) of its devices than the sole component controls. The PSCs with the ZnO NCs/PDINO CIL also exhibit good tolerance to the CIL thickness, and the PM6:Y6 and PM6:BTP-eC9 devices can achieve high PCEs of over 15% at the CIL thickness of 70 nm. Further, the ZnO NCs/PDINO devices show better stability than those with sole ZnO NCs or PDINO. Our results provide a new way to construct potential CILs for high performance PSCs.
Keywords: ZnO nanocrystals; cathode interface layer; perylene diimides functionalized with amino oxide; polymer solar cells; thickness insensitivity.