Synthesis, characterization and application of a zirconium-based MOF-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(VI) from wastewater prior to its spectrophotometric determination

Marzieh Sharifi-Rad; Massoud Kaykhaii; Mostafa Khajeh; Alireza Oveisi

doi:10.1186/s13065-022-00821-1

Synthesis, characterization and application of a zirconium-based MOF-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(VI) from wastewater prior to its spectrophotometric determination

BMC Chem. 2022 Apr 16;16(1):27. doi: 10.1186/s13065-022-00821-1.

Authors

Marzieh Sharifi-Rad¹, Massoud Kaykhaii^{2

3}, Mostafa Khajeh⁴, Alireza Oveisi⁴

Affiliations

¹ Department of Chemistry, Faculty of Sciences, University of Sistan and Baluchestan, Zahedan, Iran.
² Department of Chemistry, Faculty of Sciences, University of Sistan and Baluchestan, Zahedan, Iran. kaykhaii@chem.usb.ac.ir.
³ Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, Gdansk, Poland. kaykhaii@chem.usb.ac.ir.
⁴ Department of Chemistry, University of Zabol, Zabol, Iran.

Abstract

Background: A zirconium-based metal-organic framework (Zr-MOF), named MOF-808, was synthesized and fully characterized by solvo-thermal method and functionalized by isonicotinic acid and employed as an efficient adsorbent for selective extraction and preconcentration of uranyl ions from water and waste water samples in a batch solid phase extraction.

Results: Parameters affecting extraction such as volume and pH of the sample solution, the amount of sorbent, type and volume of eluting solvent, and adsorption and desorption times were investigated and optimized. Under the optimized conditions, high extraction efficiency was observed with a limit of detection of 0.9 µg L^{- 1} for uranyl ions and relative standard deviations were found to be better than 2.1% in the range of 0.07-1000 µg L^{- 1}.

Conclusions: These results indicated that the above procedure is fast, inexpensive, effective, reliable, applicable and organic solvent-free and showed the highly performance and stability of the Zr-MOF in SPE based analytical techniques.

Keywords: MOF-808; Metal organic framework; Sample preparation; Spectrophotometry; Uranium; Wastewater analysis.