Synthesis and magnetic properties of sub-nanosized iron carbides on a carbon support

RSC Adv. 2022 Jan 25;12(6):3238-3242. doi: 10.1039/d1ra09191c. eCollection 2022 Jan 24.

Abstract

Iron carbide clusters with near-sub-nanometer size have been synthesized by employing a tetraphenylmethane-cored phenylazomethine dendrimer generation 4 (TPM-DPAG4) as a molecular template. Magnetic measurements reveal that these iron carbide clusters exhibit a magnetization-field hysteresis loop at 300 K. The data indicate that these iron carbide clusters are ferromagnets at room temperature.