In this work, a series of colloidal gold nanoparticles with controllable sizes were anchored on carbon nanotubes (CNT) for the aerobic oxidation of benzyl alcohol. The intrinsic influence of Au particles on the catalytic behavior was unraveled based on different nanoscale-gold systems. The Au/CNT-A sample with smaller Au sizes deserved a faster reaction rate, mainly resulting from the higher dispersion degree (23.5%) of Au with the available exposed sites contributed by small gold particles. However, monometallic Au/CNT samples lacked long-term stability. CeO2 was herein decorated to regulate the chemical and surface structure of the Au/CNT. An appropriate CeO2 content tuned the sizes and chemical states of Au by electron delivery with better metal dispersion. Small CeO2 crystals that were preferentially neighboring the Au particles facilitated the generation of Au-CeO2 interfaces, and benefited the continuous supplementation of oxygen species. The collaborative functions between the size effect and surface chemistry accounted for the higher benzaldehyde yield and sustainably stepped-up reaction rates by Au-Ce5/CNT with 5 wt% CeO2.
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