Maltodextrins are inexpensive, water-soluble starch hydrolysis products composed of high molecular weight polysaccharide molecules. This feature allows their water solutions to be processed by electrospinning to produce bio-based microfibrous mats. Also, the presence of hydroxyl functions along the maltodextrin's backbone enables cross-linking reactions to be performed, necessary to overcome the intrinsic solubility of the starting material, by exploiting suitable functional molecules. In this work, the electrospinning process to obtain fibre deposition from water solutions of five different commercial maltodextrins was firstly optimized. Well-defined fibres with diameters ranging between 1.1 μm and 1.5 μm were successfully obtained using water as the unique solvent. Subsequently, the same maltodextrin-containing water solutions with citric acid added were then processed again. The presence of citric acid did not hinder the spinnability of the studied systems, while the possibility to achieve a one-step thermal curing of the obtained fibres was proved via solubility tests, TGA, and FTIR-ATR analyses. Eventually, bio-based cross-linked mats with fibre diameters ranging from 0.7 μm to 1.4 μm were obtained from the electrospinning of commercial maltodextrins and citric acid, employing water as the unique solvent and environmentally friendly curing processes. This approach enables the reported mats to be further studied for environmental, pharmaceutical, and medical applications.
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