Catalyzed ring transformation of cyclic N-aryl-azadiperoxides with participation of α,ω-dithiols

Nataliya N Makhmudiyarova; Kamil R Shangaraev; Irina R Ishmukhametova; Askhat G Ibragimov; Usein M Dzhemilev

doi:10.1039/d0ra09758f

Catalyzed ring transformation of cyclic N-aryl-azadiperoxides with participation of α,ω-dithiols

RSC Adv. 2021 Jan 21;11(7):4235-4236. doi: 10.1039/d0ra09758f. eCollection 2021 Jan 19.

Authors

Nataliya N Makhmudiyarova¹, Kamil R Shangaraev¹, Irina R Ishmukhametova¹, Askhat G Ibragimov¹, Usein M Dzhemilev¹

Affiliation

¹ Institute of Petrochemistry and Catalysis, Russian Academy of Sciences 141 Prospekt Oktyabrya 450075 Ufa Russian Federation natali-mnn@mail.ru.

Abstract

Co(OAc)₂-catalyzed ring transformation reaction of 10-aryl-7,8,12,13-tetraoxa-10-azaspiro[5.7]tridecanes with α,ω-dithiols (ethane-1,2-, propane-1,3-, butane-1,4-, pentane-1,5-, and hexane-1,6-dithiols, 3,6-dioxaoctane-1,8-dithiol) giving 3-aryl-1,5,3-dithiazacyclanes was studied.