Owing to an unmatched combination of power and energy density along with cyclic stability, the Li-ion battery has qualified itself to be the highest performing rechargeable battery. Taking both transportable and stationary energy storage requirements into consideration, Li-ion batteries indeed stand tall in comparison to any other existing rechargeable battery technologies. However, graphite, which is still one of the best performing Li-ion anodes, has specific drawbacks in fulfilling the ever-increasing energy and power density requirements of the modern world. Therefore, further research on alternative anode materials is absolutely essential. Equally important is the search for and enhanced use of right earth abundant materials for battery electrodes so as to bring down the costs of the battery systems. In this spotlight article, we discuss the current research progress in the area of alternative anode materials for Li-ion battery, putting our own research work over the past several years into perspective. Starting from conversion anode systems like oxides and sulfides, to insertion cum alloying systems like transition metal carbides, to molecularly engineered open framework systems like metal organic frameworks (MOFs), covalent organic frameworks (COFs), and organic-inorganic hybrid perovskites (OIHPs), this spotlight provides a complete essence of the recent developments in the area of alternative anodes. The possible and potential impact of these new anode materials is detailed and discussed here.
Keywords: Li-ion batteries; anodes; carbides; covalent-organic frameworks (COFs); hybrid perovskites; metal−organic frameworks (MOFs); oxides; sulfides.