Fabrication of Mn3O4-CeO2-rGO as Nanocatalyst for Electro-Oxidation of Methanol

Nanomaterials (Basel). 2022 Apr 2;12(7):1187. doi: 10.3390/nano12071187.

Abstract

Recently, the use of metal oxides as inexpensive and efficient catalysts has been considered by researchers. In this work, we introduce a new nanocatalyst including a mixed metal oxide, consisting of manganese oxide, cerium oxide, and reduced graphene oxide (Mn3O4-CeO2-rGO) by the hydrothermal method. The synthesized nanocatalyst was evaluated for the methanol oxidation reaction. The synergetic effect of metal oxides on the surface of rGO was investigated. Mn3O4-CeO2-rGO showed an oxidation current density of 17.7 mA/cm2 in overpotential of 0.51 V and 91% stability after 500 consecutive rounds of cyclic voltammetry. According to these results, the synthesized nanocatalyst can be an attractive and efficient option in the methanol oxidation reaction process.

Keywords: Mn3O4-CeO2-rGO; cyclic voltammetry; methanol oxidation; nanocatalyst.