Rainfall runoff is one of the important sources of urban river pollution. In order to understand the pollution characteristics of rainfall runoff, the synchronous sampling and monitoring of rainfall runoff in the old urban area of Nanning were carried out; the pollution condition, initial scouring effect, and pollution contribution ratio of different underlying surfaces under different rainfall conditions were analyzed; and the calculation method and influence factor analysis of initial scouring of runoff pollution were discussed. According to the underlying surface of the vegetable market in the old urban area, the selection standard and necessity of the underlying surface of rainfall runoff were discussed. The results showed that the average concentration (EMC) of COD and TSS in roads and vegetable markets were greater than those in green spaces and roofs in the runoff pollution of the old urban area of Nanning, and the EMC values of nutrient pollutants in field rainfall runoff were ranked in decreasing order as vegetable markets, green spaces, roofs, and roads. Under the condition of heavy rain, each underlying surface had an obvious initial scouring effect, the average value of initial scouring coefficient (b) was 0.67, and there were many pollutants transported by roads and green spaces at the initial stage. Under light rain and moderate rain conditions, there was no obvious initial scouring effect, and the average b values were 0.83 and 0.94, respectively. The b value calculated by the whole process was preferred for evaluating the scouring effect. Based on multivariate statistical analysis, the EMC value of TSS in road runoff was significantly positively correlated with the total rainfall duration (RD), and the EMC value of TN in green land runoff was significantly negatively correlated with the average rainfall intensity (ARI). Whether the vegetable market was considered as the underlying surface had a great impact on the calculation results of nutrient pollution load but had little impact on the calculation results of COD and TSS load. The difference percentage of nutrient pollution load under heavy rain reached 80%. Under this condition, the difference percentage of pollutant EMC between the road and vegetable market reached 1012%.
Keywords: first flush effect; old urban area; pollution characteristics; pollution tracing; rainfall runoff; underlying surface.