In recent years, flexible energy storage devices have attracted the growing demand for flexible electronic systems. Therefore, research on reliable electrodes with high mechanical flexibility and good electronic and lithium-ion conductivity has become critical. Carbon-coated Li4Ti5O12 (LTO) nanostructures find essential applications in high-performance lithium-ion batteries (LiBs). Nevertheless, the conventional copper current collector with a thickness of several micrometers accounts for a large proportion of the LiB, making the low-energy density LiB with much less flexibility. Here, hundred nm-thick (LTO/Cu) copper foil-LTO nanostructures are fabricated using a scalable and straightforward process which can be assembled into a film into a flexible, lightweight electrode by etching a conventional copper foil to form an ultra-thin copper layer for LIBs (<1 μm). This process provides essential flexibility to the as-prepared electrode and provides template support for simple fabrication. The LiB cell using the novel LTO/Cu as the anode exhibits an energy capacity of 123 mA h/g during 40 charge-discharge cycles at a 0.1C rate. Besides, the coulombic efficiency of the LiB using LTO/Cu remains over 99% after 40 cycles. These results show the uses of this novel anode and its potential in high-density and flexible commercial lithium-ion batteries.
© 2022 The Authors. Published by American Chemical Society.