Enhancement of Chiroptical Responses of trans-Bis[(β-iminomethyl)naphthoxy]platinum(II) Complexes with Distorted Square Planar Coordination Geometry

Masahiro Ikeshita; Sho Furukawa; Takahiro Ishikawa; Kana Matsudaira; Yoshitane Imai; Takashi Tsuno

doi:10.1002/open.202200061

Enhancement of Chiroptical Responses of trans-Bis[(β-iminomethyl)naphthoxy]platinum(II) Complexes with Distorted Square Planar Coordination Geometry

ChemistryOpen. 2022 Apr;11(4):e202200061. doi: 10.1002/open.202200061. Epub 2022 Mar 29.

Authors

Masahiro Ikeshita¹, Sho Furukawa¹, Takahiro Ishikawa¹, Kana Matsudaira², Yoshitane Imai², Takashi Tsuno¹

Affiliations

¹ Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, 275-8575, Narashino, Chiba, Japan.
² Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, 577-8502, Higashi, Osaka, Japan.

Abstract

Invited for this month's cover picture are the groups of Masahiro Ikeshita and Takashi Tsuno at Nihon University and Yoshitane Imai at Kindai University (Japan). The cover picture shows the comparison of circularly polarized luminescence (CPL) properties of square planar platinum(II) complexes with different coordination geometry. Computational studies have been carried out to investigate these structure-dependencies, and revealed that the distortion of the coordination geometry results into an enhancement the chiroptical responses of these compounds. Read the full text of their Research Article at 10.1002/open.202100277.

MeSH terms

Humans
Japan
Luminescence*
Platinum*

Substances

Platinum